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You have to go to the Battle Frontier in Pokemon Emerald, as this video shows: http://www.youtube.com/watch?v=zrm96BXR884

If you are playing Pokemon Gold, Silver and Crystal you will find him blocking the road on route 36. But I warn you, he will do anything not to be caught.

This is a really good walkthrough for Crystal in YouTube on how to catch it :)

http://www.youtube.com/watch?v=wAUKM2zn7n8

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