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Complete the Waters of Life main quest and you will eventually run into the Brotherhood of Steel and they will teach you. Also if you download the Operation Ancorage you automaticlly get power armor training(be sure to glitch the Simulation armor) it dosent get damaged theres a suit in the vault along with a Gaess Rifle, Trench Knife, Winterized armor, The Sword that the Commander carrys, and a few other things after you get the stuff the outcasts will fight it out allowing you to recive a gataling laser, and assorted weapons