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Simple way is kill someone who has it or wait for them to die through other means. Both DLCs offer power armor as a reward but Anchorage will give you power armor training which you will need to be able to use it. Note: A sure-fire way to get basic Power Armor is by playing through the main storyline until you are in DC and attempting to get to the GNR building. When you first meet the Brotherhood of Steel members fighting against Super Mutants, you can find one of them lying dead on a cot further up the path.