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to be able to join the brotherhood of steel you must have Broken Steel dlc and must have done the main quest called take it back after that you woke up 2 weeks later because you got knocked unconcious at the purifier because of the energy spike after you woke up Elder Lyons promoted you into a Brotherhood of Steel knight and sometimes when you go near brotherhood of steel soldiers they call you sir knight and you can talk to the initiates and they dont treat you like an outsider.

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