According to (Pokémon) Bulbapedia:
Start: Growl and Charm
Level 6: Metronome
Level 10: Sweet Kiss
Level 15: Yawn
Level 19: Encore
Level 24: Follow me
Level 28: Wish
Level 33: Ancient Power
Level 37: Safeguard
Level 42: Baton Pass
Level 46: Double Edge
Level 51: Last Resort
